Fire Earth

Earth is fighting to stay alive. Mass dieoffs, triggered by anthropogenic assault and fallout of planetary defense systems offsetting the impact, could begin anytime!

Posts Tagged ‘atmosphere’

4.5 times more NF3 in atmosphere than thought

Posted by feww on October 24, 2008

Scripps News Release
Scripps Institution of Oceanography

Potent Greenhouse Gas More Prevalent in Atmosphere than Previously Thought

NF3, a greenhouse gas used in manufacture of computer displays, flat panel televisions, microcircuits, solar panels is 17,000 times more powerful at warming the atmosphere than carbon dioxide

Scripps Institution of Oceanography/UC San Diego

Nitrogen trifluoride (NF3), a powerful greenhouse gas, is about 4.5 times more prevalent in the atmosphere than previously thought, say researchers at Scripps Institution of Oceanography at UC San Diego.

[A 3-d Space-filling model of nitrogen trifluoride. ]

Nitrogen trifluoride (NF3), a potent greenhouse gas used in the plasma etching of silicon wafers, has a global warming potential (GWP) 17,000 times greater than CO2 over a 100 year period, and with an estimated atmospheric lifetime of about 750 years.

Atmospheric measurements of nitrogen trifluoride (NF3) were made using new analytical techniques by a team at Scripps shows that the amount of the gas in the atmosphere in 2008 was about 5,400 metric tons, 4.5 times higher than previously thought,  and was increasing at about 11 percent per year.

Geochemistry professor Ray Weiss who lead the research team said: “Accurately measuring small amounts of NF3 in air has proven to be a very difficult experimental problem, and we are very pleased to have succeeded in this effort.”

The research will be published in Geophysical Research Letters, a journal of the American Geophysical Union (AGU) on October 31.

Previously, emissions of NF3 were considered too low to be a significant contributor to global warming and were therefore omitted from the Kyoto Protocol, the agreement to reduce greenhouse gas emissions signed by 182 countries in 1997.

Environmental Impact of NF3 Gas at Current levels

  • NF3 is about 17,000 times more effective a global warming agent than an equivalent mass of CO2.
  • Persists five times longer in the atmosphere than carbon dioxide.
  • [Fortunately] Contributes only about 0.04 percent [at its current application levels] to the overall global warming caused by the anthropogenic carbon dioxide emissions.

Nitrogen trifluoride has been the industries’ preferred alternative to perfluorocarbons, also potent greenhouse gases, as it was thought industrial applications broke down about 98 percent of the NF3 and only about 2 percent of the gas escaped into the atmosphere.  (Source)

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How Dirty Is Your Money?

Posted by feww on August 6, 2008

How Much CO2 Does Your Money Produce?

Did you know?

Each dollar you earn (or spend) produces 450g of CO2 pollution!

Original Entry >> Carbon Footprint of Your Dollar

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Oceans, Where Life Started, Are Dying – Part IV

Posted by feww on May 26, 2008

Wild Facts Series: Just when you thought the oceans were dying painlessly!

Carbon Emissions Make Oceans Corrosive!

‘Acidified’ Water Threatens Marine Life on the Continental Shelf from Canada to Mexico: NOAA

Researchers found evidence of corrosive water about 20 miles off the west coast of North America from Canada to Mexico last summer. The ocean water on the western North American continental shelf was previously thought not to be “acidified.”

“Ocean acidification” is caused by the ocean’s absorption of carbon dioxide (CO2) from the atmosphere, a process which makes water corrosive.


Effects of increasing carbon dioxide and temperature on coral reefs. (NOAA Coral Reef Watch)

“Acidification of the Earth’s ocean water could have far-reaching impacts on the health of our near-shore environment, and on the sustainability of ecosystems that support human populations through nourishment and jobs,” said Richard W. Spinrad, NOAA assistant administrator for oceanic and atmospheric research. “This research is vital to understanding the processes within the ocean, as well as the consequences of a carbon-rich atmosphere.”

“Our findings represent the first evidence that a large section of the North American continental shelf is seasonally impacted by ocean acidification,” said Feely. “This means that ocean acidification may be seriously impacting marine life on our continental shelf right now.”

“While this absorption provides a great service to humans by significantly reducing the amount of greenhouse gases in the atmosphere and decreasing the effects of global warming, the change in the ocean chemistry affects marine life, particularly organisms with calcium carbonate shells, such as corals, mussels, mollusks, and small creatures in the early stages of the food chain,” said Feely.

NOAA said: “Previous studies found ocean acidification at deeper depths farther from shore. The researchers said that the movement of the corrosive water appears to happen during the upwhelling season during the spring and summer, when winds bring CO2 -rich water up from depths of about 400-600 feet onto the continental shelf. The water that upwells off of the North American Pacific coast has been away from the surface for about 50 years.


Typical coral-reef community observed in the U.S. Virgin Islands. [Species lables: the image to view labels: Ma, boulder star coral (Montastrea annularis); Dc, knobby brain coral (Diploria clivosa); Pa, mustard hill coral (Porites astreoides); Pp, finger coral (Porites porites); D, dead coral (probably Porites astreoides); O, octocoral (soft coral); S, sponge.] Photograph by Nathan Smiley, USGS.

The field study collected samples from Queen Charlotte Sound, Canada, to San Gregorio Baja California Sur, Mexico. The closest they found corrosive water was about four miles off of the northern California coast.”

“We did not expect to see this extent of ocean acidification until the middle to the end of the century,” said Sabine. “Because of this effort, we have a baseline for future observations as we continue to study and monitor the relationship of biological and physical processes and their ability to respond to ocean acidification.”

“We did not expect to see this extent of ocean acidification until the middle to the end of the century,” said Sabine. “Because of this effort, we have a baseline for future observations as we continue to study and monitor the relationship of biological and physical processes and their ability to respond to ocean acidification.”

“When the upwelled water was last at the surface, it was exposed to an atmosphere with much less CO2 than today and future upwelled waters will probably be more acidic than today’s because of increasing atmospheric CO2,” said Hales, a professor of chemical oceanography, who is also funded by NASA.

“We don’t know how this will affect species living in the zone below the level of the lowest tides, out to the edge of the continental shelf,” said Ianson, an oceanographer. “We do know that organisms like corals or pteropods are affected by water saturated with CO2. The impacts on other species, such as shellfish and other juvenile fish that have economic significance, are not yet fully understood.”

“In Baja California, we have several Mediterranean-climate coastal lagoons where the main external physical and biogeochemical forcing is from the neighboring coastal ocean, strongly influenced by upwelling,” said Hernandez-Ayon, a coastal oceanographer. “We are concerned about these areas because they play an important role as nurseries and feeding grounds of juvenile fish populations but are also are ideal sites for shellfish aquaculture.” More …

What is Bleaching?

Corals are very sensitive to temperature change: a 1–2º C change in local temperature above their normal summer maximum can lead to a phenomenon called ‘bleaching’, whereby the corals expel their vital algal symbionts (algae which live in the cells of the coral), leaving the coral tissues translucent.


Bleached Coral (Pocillopora) NOAA’s Pacific Islands Fisheries Science Center of the National Marine Fisheries Service.

In 1998, a single bleaching event led to the loss of almost 20% of the world’s living coral. Corals can recover from these events but repeated episodes are likely to weaken the coral ecosystem, making them more susceptible to disease and causing a loss of biodiversity. (Source)

How will ocean acidification affect marine life?

Corals, calcareous phytoplankton, mussels, snails, sea urchins and other marine organisms use calcium (Ca) and carbonate (CO3) in seawater to construct their calcium carbonate (CaCO3) shells or skeletons. As the pH decreases, carbonate becomes less available, which makes it more difficult for organisms to secrete CaCO3 to form their skeletal material. For animals in general, including invertebrates and some fish, CO2 accumulation and lowered pH may result in acidosis, or a build up of carbonic acid in the organism’s body fluids. This can lead to lowered immune response, metabolic depression, behavioral depression affecting physical activity and reproduction, and asphyxiation. Since the oceans have never experienced such a rapid acidification, it is not clear if ecosystems have the ability to adapt to these changes (1,2). Effects of ocean acidification on organisms and ecosystems are still poorly understood. Over the last few years, research has intensified significantly to fill the many knowledge gaps. (Source)

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Penguins DDT Contamination Levels Still High

Posted by feww on May 10, 2008

Just when you thought penguins fared better than polar bears!

Just when you thought the Antarctic marine life had only a few minor problems like the climate change and ozone hole to worry about, but were otherwise safe from other harms like ingesting plastic trash, or growing a “skin” rash from pesticide contamination, it has been revealed that the deadly pesticide DDT, banned in most countries more than 35 years ago, stills show up in penguins in Antarctica.

A researcher has blamed the DDT contamination on the chemical’s accumulation of the poison in melting glaciers.

“DDT, along with a lot of other of these organic contaminants, actually travel through the atmosphere … toward the polar regions by a process of evaporation and then condensation in cooler climates,” according to Heidi Geisz of the Virginia Institute of Marine Science.

The DDT contamination in the Adelie penguins was first discovered in 1964. The contamination level rose in the 1970s and has stayed stable since then, Geisz said.


Mating Adelie penguins at Cape Adare in Ross Sea, Antarctica January of 2001. This file is licensed under the Creative Commons Attribution ShareAlike license versions 2.5, 2.0, and 1.0 (Credit: Mila Zinkova)

In 1962, Silent Spring by American biologist Rachel Carson was published. The book cataloged the environmental impacts of the indiscriminate spraying of DDT in the US and questioned the logic of releasing large amounts of chemicals into the environment without fully understanding their effects on ecology or human health. The book suggested that DDT and other pesticides may cause cancer and that their agricultural use was a threat to wildlife, particularly birds. Its publication was one of the signature events in the birth of the environmental movement. Silent Spring resulted in a large public outcry that eventually led to most uses of DDT being banned in the US in 1972. DDT was subsequently banned for agricultural use worldwide, but its limited use in disease vector control continues to this day in certain parts of the world and remains controversial. (source)

Is it possible that New Zealand is still using DDT in large quantities?

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